Have a look at the highlighted cell, what value can't that cell be?
There is already a 1, 5, 6, and 7 in this row.
There is already a 2, 8, 9 in this column.
There is already a 3 and 6 in the same region.
Put all of this together and we know that the highlighted cell can't be any of 1, 2, 3, 5, 6, 7, 8 or 9.
The only value (Single Candidate) left is 4, i.e. the highlighted cell must be 4.